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141.
142.
Jerzy Cioslowski 《Theoretical chemistry accounts》1992,81(4-5):319-327
Summary A new index, called the differential density matrix overlap (DDMO), is proposed for assessment of the electron correlation effects in atoms and molecules. DDMO can be easily calculated as the negative value of the correlation energy derivative with respect to the relative position of the occupied and virtual orbitals. DDMO is transparent to physical interpretation. It can serve as a tool for analyzing the accuracy of approximate electron correlation methods and the validity of the Hartree-Fock wavefunction as the zeroth-order approximation. The properties of DDMO are discussed using test calculations on 11 atoms and molecules as an example. 相似文献
143.
On the properties of solutions to the Goursat-Darboux problem with boundary and distributed controls
N. I. Pogodaev 《Siberian Mathematical Journal》2007,48(5):897-912
We consider a control system described by the Goursat-Darboux equation. The system is controlled by distributed and boundary controls. The controls are subject to the constraints given as multivalued mappings with closed, possibly nonconvex, values depending on the phase variable. Alongside the initial constraints, we consider the convexified constraints and the constraints whose values are the extreme points of the convexified constraints. We study the questions of existence of solutions and establish connections between the solutions under various constraints. 相似文献
144.
General limit theorems are established for l~p-valued Gaussian random fields indexed by a multidimensional parameter,which contain both almost sure moduli of continuity and limits of large increments for the l~p-valued Gaussian random fields under(?)explicit conditions. 相似文献
145.
146.
In a seminal paper, Martin Clark (Communications Systems and Random Process Theory, Darlington, 1977, pp. 721–734, 1978) showed how the filtered dynamics giving the optimal estimate of a Markov chain observed in Gaussian noise can be expressed
using an ordinary differential equation. These results offer substantial benefits in filtering and in control, often simplifying
the analysis and an in some settings providing numerical benefits, see, for example Malcolm et al. (J. Appl. Math. Stoch.
Anal., 2007, to appear).
Clark’s method uses a gauge transformation and, in effect, solves the Wonham-Zakai equation using variation of constants.
In this article, we consider the optimal control of a partially observed Markov chain. This problem is discussed in Elliott
et al. (Hidden Markov Models Estimation and Control, Applications of Mathematics Series, vol. 29, 1995). The innovation in our results is that the robust dynamics of Clark are used to compute forward in time dynamics for a simplified
adjoint process. A stochastic minimum principle is established. 相似文献
147.
The paper is devoted to statistical nonparametric estimation of multivariate distribution density. The influence of data pre-clustering
on the estimation accuracy of multimodal density is analyzed by means of the Monte Carlo method. It is shown that the soft
clustering is more advantageous than the hard one. While a moderate increase in the number of clusters also increases the
calculation time, it considerably reduces the estimation error. 相似文献
148.
带干扰的Erlang(2)风险模型的不破产概率 总被引:1,自引:0,他引:1
本文讨论了带干扰的Erlang(2)风险模型,通过构造一个延迟更新过程,我们得到了不破产概率满足的积分-微分方程,进而得到了不破产概率的明确表达式. 相似文献
149.
V. V. Panić A. B. Dekanski S. K. Milonjić V. B. Mišković-Stanković B. Ž. Nikolić 《Russian Journal of Electrochemistry》2006,42(10):1055-1060
Electrocatalytic properties of RuO2/Ti anode with different coating masses, which are prepared by the alkoxide sol-gel procedure, are investigated in chlorine
and oxygen evolution reactions by polarization measurements and electrochemical impedance spectroscopy in H2SO4 and NaCl electrolytes. According to polarization measurements, the activity of anodes at overpotentials below 100 mV is independent
of coating mass. However, impedance measurements above 100 mV reveal changes in the activity of anodes in chlorine evolution
reaction for different coating masses. The diffusion limitations related to the evolved chlorine are registered in low-frequency
domain at 1.10 V (SCE), diminishing with the increase in potential to the 1.15 V (SCE). The observed impedance behavior is
discussed with respect to the activity model for activated titanium anodes in chlorine evolution reaction involving formation
of gas channels within porous coating structure. Gas channels enhance the mass transfer rate similarly to the forced convection,
which also increases the activity of anode. This is more pronounced for the anode of greater coating mass due to its more
compact surface structure. The more compact structure appears to be beneficial for gas channels formation.
Published in Russian in Elektrokhimiya, 2006, Vol. 42, No. 10, pp. 1173–1179.
The text was submitted by the authors in English. 相似文献
150.